Nội dung text ideal gas solve.pdf
Av`k© M ̈vm I M ̈v‡mi MwZZË¡ HSC Preparation 1 `kg Aa ̈vq Av`k© M ̈vm I M ̈v‡mi MwZZË¡ Ideal Gas and Kinetics of Gases ACS Physics Department Gi g‡bvbxZ cÖkœmg~n 1| w ̄’i ZvcgvÎvq 1.5 105 Nm–2 Pv‡c wbw`©ó wKQz M ̈v‡mi AvqZb 0.003 m2 ; 9 105 Nm–2 Pv‡c M ̈vmwUi AvqZb KZ? mgvavb: P1V1 = P1V2 1.5 105 0.003 = 5 105 V2 V2 = 9 10–4 m 3 (Ans.) 2| w ̄’i ZvcgvÎvq 0.75 m (cvi`) Pv‡c 50 10–6 m 3 nvB‡Wav‡Rb M ̈vm ivLv Av‡Q| hw` Pvc e„w×i d‡j M ̈v‡mi AvqZb 38 10–6 m 3 nq Z‡e Pvc e„w×i cwigvY KZ? mgvavb: P1V1 = P1V2 hg V1 = P2V2 0.76 13600 9.8 50 10–6 = P2 38 10–6 P2 = 133280 Pa Pvc e„w× = 133280 – (0.76 9.8 13600) Pa = 31987.2 Pa (Ans.) 3| GKwU cv‡Î 0C ZvcgvÎvq wKQz M ̈vm iwÿZ Av‡Q| KZ ZvcgvÎvq M ̈v‡mi Pvc 0C ZvcgvÎvi Pv‡ci GK Z...Zxqvsl n‡e? (aiv hvK, cv‡Îi AvqZb AcwiewZ©Z _v‡K? mgvavb: P1 T1 = P2 T2 P 273 = P 3 T2 T2 = 91 k 4| GKwU d¬v‡· 30C ZvcgvÎv Ges 1 evqygÛjxq Pv‡c wKQz evZvm Ave× Av‡Q| GLb d¬v‡·i gyL wQwc w`‡q AvUwK‡q G‡K DËß Kiv ïiæ n‡jv| wQwcwU Lyj‡Z hw` 4 evqygÐjxq Pv‡ci cÖ‡qvRb nq Z‡e KZ ZvcgvÎv ch©šÍ G‡K DËß Ki‡j wQwcwU Ly‡j hv‡e? mgvavb: P1 T1 = P2 T2 1 (30 + 273) = 4 T2 T2 = 1212 k (Ans.) 5| wQwc AvUv †evZ‡j ̄^vfvweK Pv‡c 27C ZvcgvÎv wKQz M ̈vm Av‡Q| evZv‡mi ZvcgvÎv 50C-G DbœxZ Ki‡j M ̈v‡mi Pvc KZ n‡e? mgvavb: P1 T1 = P2 T2 101325 (27 + 273) = P2 (50 + 273) P2 = 109093.25 Pa (Ans.) 6| w ̄’i Pv‡c KZ ZvcgvÎvq 0C ZvcgvÎvi M ̈v‡mi AvqZb wØ ̧Y n‡e? mgvavb: V1 T1 = V2 T2 v 273 = 2v T2 T2 = 546 k (Ans.) 7| w ̄’i Pv‡c 27C ZvcgvÎvq 100 m3 M ̈v‡mi ZvcgvÎv KZ n‡j AvqZb 150 m3 n‡e? mgvavb: V1 T1 = V2 T2 100 (27 + 273) = 150 T2 T2 = 450 k (Ans.) 8| 27C ZvcgvÎvq 0.76m cvi` Pv‡c GKwU M ̈v‡mi AvqZb 45 wjUvi| KZ Pv‡c 77C ZvcgvÎvq H M ̈v‡mi AvqZb 30 wjUvi n‡e? mgvavb: P1V1 T1 = P2V2 T2 0.76 45 10–3 (27 + 273) = P2 30 10–3 (77 + 273) P2 = 1.33m (Hg) (Ans.) 9| 10C wWwMÖ ZvcgvÎvq 1 L evqy‡K Zvc †`Iqv n‡jv| KZ ZvcZvÎvq Zvi AvqZb I Pvc wØ ̧Y n‡e? mgvavb: P1V1 T1 = P2V2 T2 P 1 (10 + 273) = 2P 2 1 T2 T2 = 1132 k (Ans.) 10| GKwU wmwjÛv‡i iwÿZ M ̈v‡mi AvqZb 1 10–2 m 3 , ZvcgvÎv 300 K Ges Pvc 2.5 105 Nm–2 | ZvcgvÎv w ̄’i †i‡L wKQz Aw·‡Rb †ei K‡i †bIqvi ci Pvc K‡g 1.3 105 Nm–2 nq| e ̈eüZ Aw·‡R‡bi fi KZ? mgvavb: e ̈eüZ Aw·‡R‡bi †gvjmsL ̈v, n = n1 – n2 = P1V RT – P2V RT = 1 10–2 8.314 300 (2.5 105 – 1.3 105 ) = 0.48 mol e ̈eüZ Aw·‡R‡bi fi = (0.48 32)g = 15.4 gm 11| 0C ZvcgvÎvq I GK evqygÛjxq Pv‡c 1 10–3 m 3 evqyi fi 1.3 10–3 kg| 120 evqygÛjxq Pv‡c Ges 30C ZvcgvÎv 1m3 evqyi fi †ei K‡iv? mgvavb: P1V1 T1 – P2V2 T2 1 1 10–3 273 = 120 v1 (30 + 273)
2 HSC Physics 1st Paper Chapter-10 v2 = 9.25 10 –6 m 3 GLv‡b, 9.25 10–6m 3 evqyi IRb 1.3 10–3 kg 1m3 evqyi IRb = 1.3 10–3 9.25 10–6 kg = 140.55 kg (Ans.) 12| 20C ZvcgvÎvq 1 wjUvi evqy‡Z Zvc †`Iqv n‡jv, †h ch©šÍ Zvi AvqZb I Pvc wØ ̧Y bv nq| evqyi ZvcgvÎv †ei K‡iv| mgvavb: P1V1 T1 – P2V2 T2 P 1 (20 + 273) = 2P 1 2 T2 T2 = 1172 k (Ans.) 13| ̄^vfvweK Pvc I ZvcgvÎvq evqyi NbZ¡ 1.29 kg m–3 30C ZvcgvÎvq Ges 75 10–2 m cvi` Pv‡c H evqyi NbZ¡ wbY©q K‡iv| mgvavb: 1T1 P1 – 2T2 P2 1.29 273 0.76 = 2 (30 + 273) 75 10–2 2 = 1.15 kgm–3 (Ans.) 14| 0C ZvcgvÎv I 0.76 m Pv‡ci evZv‡mi Nb‡Z¡i mv‡_ 27C ZvcgvÎv I 0.75m Pv‡ci Nb‡Z¡i Zzjbv K‡iv? mgvavb: 0C ZvcgvÎvq evZv‡mi NbZ¡ = 1 27C ZvcgvÎvq evZv‡mi NbZ¡ = 2 P1 1T1 = P2 2 T2 0.76 1 273 = 0.75 2 (27 + 273) 2 1 = 0.898 2 = 0.898 1 A_©vr, 2 < 1 1 †ewk = 1 – 0.898 1 1 100% = 10.197% 15| 0C ZvcgvÎvq I 1 evqygÛjxq Pv‡c 1 wjUvi evqyi fi 1.3 10–3 kg| KZ ZvcgvÎvq 130 evqygÛjxq Pv‡c 1000 wjUvi evqyi fi 140 kg n‡e? mgvavb: 140 kg fi nq 1000 L evqyi 1.3 10–3 fi nq = 1000 1.3 10–3 140 L evqy = 9.286 10–3L evqy GLb, P1V1 T1 – P2V2 T2 1 1 273 = 130 9.286 10–3 T2 T2 = 329.56 k (Ans.) 16| GKRb Wzeyix †Kvb weï× cvwbi n«‡` 20m Mfxi cvwb‡Z KvR Kivi mgq 0.000003 m3 AvqZ‡bi evZv‡mi ey`ey` Dc‡ii w`‡K cÖevwnZ nq| evqygÛ‡ji Pvc 98000 Nm–2 n‡j, cvwbi DcwiZ‡j †c.Qv‡j cÖwZwU ey`ey‡`i AvqZb KZ n‡e? (cvwbi ZvcgvÎv me©Î mgvb a‡iv)| mgvavb: P1V1 = P2V2 (hPg + Patm) v1 = Patm v2 (20 1000 9.8 + 98000) 0.000003 = 98000 v2 v2 = 9 10–6 m 3 (Ans.) 17| †Kvb n«‡`i Zj‡`k †_‡K cvwbi DcwiZ‡j Avmvq GKwU evqy ey`ey‡`i AvqZb 5 ̧Y nq| evqygÛ‡ji Pvc 105 Nm–2 n‡j n«‡`i MfxiZv KZ? mgvavb: P1V1 = P2V2 (Patm + hg) v1 = Patm v2 (105 + h 1000 9.8) v = 105 5v h = 40.82 m (Ans.) 18| †Kv‡bv n«‡`i Zj‡`k †_‡K c„‡ô Avmvi d‡j GKwU evZv‡mi ey`ey‡`i e ̈vmva© wZb ̧Y n‡q hvq| e ̈v‡ivwgUv‡i cvi` ͇̄¤¢i D”PZv 75 cm n‡j n«‡`i MfxiZv KZ? (cvi` Gi NbZ¡ 13596 kg m–3 ) mgvavb: P1V1 = P2V2 (Patm + hg) v1 = Patm v2 (0.75 13596 9.8 + 1000 9.8) 4 3 r1 3 = 0.75 13596 9.8 4 3 (3r1) 3 h = 265.12 m (Ans.) 19| Rjvk‡qi KZ MfxiZv GKwU ey`ey‡`i AvqZb DcwiZ‡j _vKvKvjxb AvqZb A‡cÿv A‡a©K n‡e? H mgq evqygÛ‡ji Pvc 760mm cvi` Ges cvi‡`i NbZ¡ 13.6 103 kgm–3 | H mgq evqygÛ‡ji Pvc 760mm cvi` Ges cvi‡`i NbZ¡ 13.6 103 kgm–3 | mgvavb: P1V1 = P2V2 (Patm + hg) v1 = Patm v2 (760 10–3 13.6 103 9.8 + h 1000 9.8) v2 2 = 760 10–3 13.6 103 9.8 v2 h = 10.336 m (Ans.) 20| cÖgvY ZvcgvÎv I Pv‡c 8g Aw·‡R‡bi AvqZb wbY©q Ki| mgvavb: Pv = nRT 101325 v = 8 32 8.314 273 v = 5.6 10–3 m 3 21| 30C ZvcgvÎvq Ges 2atm Pv‡c GKwU †ejy‡bi g‡a ̈ 24g Aw·‡Rb M ̈vm Av‡Q| GK †gvj Aw·‡R‡bi fi 32gm, Aciw`‡K †Kvb GKwU cyKz‡ii Dcwi‡`‡k evqygÛ‡ji Pvc 1.5 atm, cvwbi NbZ¡ 1050 kgm–3 I MfxiZv 20m Ges Ab ̈ GKwU cyKz‡ii Dcwi‡`‡k evqygÛ‡ji Pvc 1.2 atm cvwbi NbZ¡ 1000 kgm–3 I MfxiZv 25m| [1 atm = 1.013 105 Pa, R = 8.314 Jmol–1K –1 Ges g = 9.8 m– 2 ]
Av`k© M ̈vm I M ̈v‡mi MwZZË¡ HSC Preparation 3 mgvavb: (K) †ejybwUi M ̈v‡mi AvqZb wbY©q Ki| Pv = nRT 2 1.013 105 v = 24 32 8.314 (30 + 273) v = 9.32 10–3 m 3 (L) †Kvb cyKz‡ii Zj‡`‡k M ̈vm fwZ© †ejy‡bi AvqZb Kg n‡e? MvwYwZKfv‡e we‡kølY Ki| 1g cyKz‡ii †ÿ‡Î Zj‡`‡k †ejy‡bi AvqZb = v1m 3 n‡j, P1V1 = P2V2 (Patm + hg) v1 = Patm v2 (1.013 105 1.5 20 9.8 1000) v1 = 1.5 1.013 105 v2 v2 = 2.2899 v1 v1 = 0.44 v2 v1 = v1 < v1 2q cyKz‡ii Zj‡`‡k †ejy‡bi AvqZb = v1 n‡j, P1V1 = P2V2 (Patm + hg) v1 = Patm v2 (1.2 1.013 105 + 25 103 9.8) 1.2 1.013 105 v1 = 1.5 1.013 105 v2 v1 = 0.332 v2 2q cyKz‡ii Zj‡`‡k M ̈vm fwZ© wejy‡bi AvqZb Kg n‡e| 22| hw` R = 8.31 JK–1 mol–1 nq Z‡e 72 cm cvi` Pv‡c Ges 27C ZvcgvÎvq 20 g Aw·‡R‡bi AvqZb wbY©q K‡iv| mgvavb: Pv = nRT PV = m RT 0.72 13.6 103 9.8 v = 20 32 8.31 (27 + 273) v = 0.0162 m3 23| n«‡`i Zj‡`k †_‡K c„ô‡`‡k Avmvq GKwU ey`ey‡`i e ̈vm wØ ̧Y nq| n«‡`i c„‡ô evqygÛjxq Pvc 100 Nm–2 n‡j, n«‡`i MfxiZv wbY©q K‡iv| mgvavb: P1V1 = P2V2 (Patm + hg) v1 = Patm v2 (105 h 1000 9.8) 4 3 d1 2 3 = 105 4 3 2 d1 2 3 (105 + 9800h) 1 8 = 105 h = 71.43 m 24| w ̄’iPv‡c 4 10–3 m 3 AvqZ‡bi †Kvb M ̈vm‡K 0C †_‡K 68.25C ch©šÍ DËß Kivi d‡j Gi AvqZb 1 10–3 m 3 e„w× †c‡j cig k~b ̈ ZvcgvÎvi gvb KZ? mgvavb: V2 = V1 (1 + ) (4 10–3 +1 10–3 ) = 4 10–3 (1+ 68.25) = 1 273 C –1 GLb, cig k~b ̈ ZvcgvÎv = t C n‡j, 0 = V1 (1 + t ) t = – 1 t = – 1 = –1 1 273 = – 273C (Ans.) 25| w ̄’i AvqZb 0C ZvcgvÎvq †Kvb M ̈v‡mi Pvc 3 105 Pa n‡j 60C ZvcgvÎvq Gi Pvc KZ n‡e? mgvavb: P1 T1 = P2 T2 3 105 273 = P2 (60 + 273) P2 = 3.659 105 Pa (Ans.) 26| 0.64 m cvi` ̄ͤ¢ Pv‡c Ges 39C ZvcgvÎv †Kvb M ̈v‡mi AvqZb 5.7 10–4 m 3 cÖgvY Pvc I ZvcgvÎvq M ̈v‡mi AvqZb KZ? mgvavb: P1V1 T1 – P2V2 T2 0.64 5.7 10–4 (39 + 273) = 0.76 v 273 v = 4.2 10–4 m 3 (Ans.) 27| w ̄’i ZvcgvÎvq 7.5 104 N.m–2 Pv‡c wbw`©ó f‡ii M ̈v‡mi AvqZb 0.006m3 | 3 105 N.m–2 Pv‡c H M ̈v‡mi AvqZb KZ n‡e? mgvavb: P1V1 = P2V2 7.5 104 0.006 = 3 105 v2 V2 = 1.5 10–3 m 3 (Ans.) 28| 20m cvwbi wb‡P GKwU ey`ey‡`i AvqZb 0.00003m3 | evqygÛ‡ji Pvc n‡j cvwbi DcwiZ‡j ey`ey`wUi AvqZb KZ n‡Z? mgvavb: P1V1 = P2V2 (Patm + hg) v1 = Patm v2 (105 20 1000 9.8) 0.00003 = 105 v2 v2 = 8.88 10–5 m 3 (Ans.) 29| 27C ZvcgvÎvi wbw`©ó f‡ii M ̈v‡mi AvqZb 0.0003 m 3 | Pvc w ̄’i †i‡L ZvcgvÎv 127C Kiv n‡j Gi AvqZb KZ n‡e? mgvavb: V1 T1 = V2 T2 0.0003 (27 + 273) = v2 (127 + 273) v2 = 4 10–4 m 3 (Ans.) 30| KZ ZvcgvÎvq †Kv‡bv M ̈v‡mi Pvc I AvqZb – 73C ZvcgvÎvq Pvc I AvqZ‡bi wZb ̧Y n‡e? mgvavb: P1V1 T1 – P2V2 T2 P1V1 (–73 + 273) = 3P1 3v1 T2 T2 = 1800 k (Ans.)
4 HSC Physics 1st Paper Chapter-10 31| w ̄’i Pv‡c 0.003 m3 AvqZ‡bi †Kv‡bv M ̈vm‡K 0C †_‡K 75C ZvcgvÎvq DËß Kiv n‡j Gi AvqZb 0.003825 m3 nq| w ̄’i Pv‡c M ̈v‡mi AvqZb cÖmviY mnM wbY©q Ki| mgvavb: V2 = V1 (1 + ) 0.003825 = 0.003 (1 + 75) 3.67 10–3 (C)–1 (Ans.) 32| cÖgvY ZvcgvÎv I Pv‡c 20g Aw·‡R‡bi AvqZb wbY©q Ki| mgvavb: PV = m RT 101325 v = 20 32 8.314 273 v = 0.014 m3 (Ans.) 33| cÖgvY ZvcgvÎv I Pv‡c GKwU †ejyb 175kg fi enb Ki‡Z cv‡i| mvg ̈ve ̄’vb †_‡K DuPz †Kv‡bv ̄’v‡b †hLv‡b e ̈v‡iv‡gwUaK Pvc 50cm cvi` Pv‡ci mgvb Ges ZvcgvÎv – 10C †mLv‡b †ejybwU KZ fvi enb Ki‡Z cvi‡e? [AvqZb AcwiewZ©Z/aaæeK a‡i] Aw·‡R‡bi AvqZb wbY©q Ki| mgvavb: 1T1 P1 – 2T2 P2 m1 v T1 P1 = m2 v T2 P2 m2 = M1T1P2 P1T2 m2 = 175 273 50 76 (– 10 + 273) m2 = 119.5 kg AvqZb = v L n‡j, v 22.4 = 119.5 32 10–3 v = 83650 L (Ans.) 34| 500cc Ges 100cc AvqZ‡bi `ywU KvPbj D‡cÿYxq AvqZ‡bi bj Øviv mshy3 Av‡Q| e ̈e ̄’vwU hLb evqy‡iva Kiv nj ZLb Af ̈šÍixY ZvcgvÎv 20C Ges Pvc 70cm Hg| hw` 100cc bj‡K 20C ZvcgvÎvq Ges 500cc bj‡K 100C ZvcgvÎvq DËß Kiv nq Z‡e e ̈e ̄’vwUi Af ̈šÍixY Pvc KZ? mgvavb: mshy3 Ae ̄’vq †gvjmsL ̈v = n n‡j, n = PV RT = 70 (500 + 100) R (273 + 20) n = 70 600 R 293 ......... (i) 1g b‡ji Rb ̈, n1 = P1V1 RT1 n1 = 100 P1 R 293 ......... (ii) 2q b‡ji Rb ̈, n2 = P1V1 RT1 n2 = P1 500 R 373 .......... (iii) GLb, n = n1 + n2 70 600 2 273 = 100P1 R 273 + 500P1 R 373 P1 = 85.23 cm (Hg) (Ans.) 35| mgAvqZ‡bi `ywU cv‡Î h_vμ‡g 48gm I 8gm O2 I He M ̈vm ivLv Av‡Q| cvÎ؇qi ZvcgvÎv h_vμ‡g 60C I 20C| GKwU D‡cÿYxq AvqZ‡bi bj Øviv cvÎØq‡K mshy3 Ki‡j mvg ̈ve ̄’vq mgMÖ e ̈e ̄’vwUi ZvcgvÎv †ei K‡iv| mgvavb: awi, e ̈e ̄’vwUi ZvcgvÎv = T n1c1 T1 = n2 c2 T2 48 32 5 2 R (60 + 273 – T) = 8 5 3 2 R {T – (20 + 273)} 15 4 (333 – T) = 3(T – 29) 1248.75 + 879 = 3 + 15 4 T T = 315.22 k (Ans.) 36| MÖx®§Kv‡j 60C ZvcgvÎvq GKwU M ̈vmc~Y© wmwjÛv‡ii wc÷‡b m kg fvi Pvcv‡j Zv f~-c„‡ô mvg ̈ve ̄’vq _v‡K| evqygЇji KvR D‡cÿv K‡i kxZKv‡j –10C ZvcgvÎvq wmwjÛviwU‡K f~-c„ô †_‡K D”PZvq ̄’vcb Ki‡j Zvi AvqZb AcwiewZ©Z _vK‡e| mgvavb: awi, h D”PZvq ̄’vcb Ki‡Z n‡e| P1 T1 = P2 T2 mg1 A mg2 A = T1 T2 g1 g2 = (60 + 273) (–10 + 273) R + b R 2 = 333 263 3 + h R = 1.125 h = 0.125 6400 km h = 801.52 km (Ans.) 37| 6 wjUvi m‡e©v”P aviYÿgZv m¤úbœ GKwU †ejyb 20C ZvcgvÎvq wbw`©ó cwigvY M ̈vm Øviv c~Y© Kiv nq ZLb Gi Pvc 3atm| cieZ©x‡Z †ejybwU‡K 15C ZvcgvÎvi †Lvjv gv‡V Iov‡Z †M‡j †d‡U hvq| (K) DÏxc‡Ki †ejybwUi †kl Pvc wbY©q Ki| mgvavb: P1 T1 = P2 T2 3 (20 + 27 + 3) = P2 (35 + 273) P2 = 3.15 atm (Ans.) (L) †ejybwU‡Z 5 wjUvi M ̈vm Øviv c~Y© Kiv n‡j dvU‡e wKbv? MvwYwZKfv‡e we‡kølY Ki| mgvavb: ÔKÕ n‡Z P2 = 3.15 atm P1V1 T1 – P2V2 T2 3 5 (20 + 273) = 3.15 v2 (35 + 273) v2 = 5.006 L (Ans.) †h‡nZz, v2 < 6 A_©vr †ejybwU dvU‡e bv|