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water -1 Carbon - chain or molecular mass of Carboxylic and. -> In you-polar Solvent ,Carboxylic said exist as cylic dimer due to intermolecular H-sonding. - S ----H -0 / 2- R r - +S -> Il O 0 - H --- Cycle contains Number of C-atoms2 Number of H-atoms-2 Number of o atoms4 -> B. P ofCarboxylic-C-chain of Carboxylic acd RCOOH -> MOOH CH3COOH CHICHLCOON B . P -> 3734(1082) < 391k (128')3414(24/C) emp of carboxylic acid & c-chain of Carboxylic seid But m. p of carboxylic ad witheven number eprepare.org

If Matom of cchain is replaced by halogen ~number of halogen atom (X3> X23X2 > Xzero) Acidic & EN of X-atom strength (f > d > Br > I) - disance of x-atom from coot group Nomenclature: HCOOH CH3COOH CH3CH2COOH Methanoic acid Ethanoic acid Propanoic acid CH3 CH2CH2 COON Butanoic acid. -> In case of branched acds, ett I CH3-CH-cook CH3-CH-CH-COON in Bi 2-methyl proponic acid 3-Bromo-2-methyl butanoica eprepare.org

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